جَاءَ زَيْدٌ الْعَالِمُ: al-ʿālimu expresses Zayd’s quality: adjective.
جَاءَ زَيْدٌ وَعَمْرٌو: ʿAmrun is coordinated by wāw, not an adjective.
جَاءَ زَيْدٌ نَفْسُهُ: nafsuhu adds emphasis.
These are teaching examples: equal case does not mean equal function.