جَاءَنِي زَيْدٌ لَا عَمْرٌو
Zayd came to me, not ʿAmr.
Here «lā» does not merely add another name. It corrects a possible mistaken belief by affirming the arrival of Zayd and negating it of ʿAmr.
Compare «Zayd and ʿAmr came» with «Zayd, not ʿAmr, came». The conjunction selects a narrower extension of the predicate; this is a rhetorical correction of attribution.