وَتَحْسَبُهُمْ أَيْقَاظًا وَهُمْ رُقُودٌ
You would think them awake, though they are asleep.
Aيقاظاً (awake) and ruqūd (asleep) are nominal descriptions. Both characterize the same group in opposed ways: what an observer supposes and what their actual state is.
The antithesis sharpens the striking picture: an appearance suggesting wakefulness is juxtaposed with actual sleep. This is more than listing two antonyms, because the opposing states explain the scene.